. First compression cI First expansion o Second compression * Second expansion * PEO2000 2 a PEO core pHI=5.5 20 40 60 ylene (M)" 20 - ~-oPEO core pH=1 3 15 - ~4 -s- PEO2670 10E~l ~15 - E 0 20 10 Area per eth ~t oxide unit 0 500 1000 1500 2000 MMA (AZ2) Figure 4-3. Isotherms of the PEO homopolymers. (Inset) Same respect to the number of ethylene oxide units. I 2500 3000 isotherms normalized with 300 600 900 MMA (AZ2) 1200 1500 Figure 4-4. Compression-expansion hysteresis plot of the PEO core (target pressure = 2 mN/m).