i SS GEOCHEMICAL AND PETROLOGIC CHARACTERIZATION OF PUMICE ARTIFACTS FROM THE MIAMI CIRCLE-BRICKELL POINT ARCHAEOLOGICAL SITE PLUS OTHER SITES IN FLORIDA - POTENTIAL PROVENANCE LOCATIONS STEPHEN A. KISH Department of Geosciences, Florida State University, Tallahassee, FL 32306-4100 E-Mail: kish@gly fsu.edu Introduction Pumice is a light-colored, highly vesicular igneous rock that normally has sufficient buoyancy to float on water. The formation of pumice is associated with the violent eruption of volcanoes, features that are not present in Florida. Wheeler (2006, this issue) reported that at least 121 pumice artifacts have been recovered from excavations at the Miami Circle- Brickell Point archaeological site (8DA12) and there are at least 30 other sites in southern Florida that contain a limited number of pumice artifacts (Figure 1). Several pumice artifacts (~3-4) also were discovered on the northwestern Gulf Coast of Florida at the Wynnhaven Beach site (80K239) during recent site studies (Ryan J. Wheeler, personal communication). A single location, the Governor Martin site (8LE853B), in the inland portion of the Florida Panhandle, near Tallahassee, Florida also produced a single pumice fragment. A majority of the pumice artifacts appear to be associated with the Glades I period (Wheeler 2006), however, material from younger sites has been discovered, including early European contact period locations suchas Governor Martin site (DeSoto winter encamp- ment); the early eighteenth century Higgs site and the early nineteenth century Indian Key site (Wheeler 2006). Radiocar- bon (‘C) dating of charcoal from the Miami Circle and adjacent Brickell Point — Sheraton site, yield calibrated ages in the range of BC 500 — AD 400 (Carr and Ricisak 2000). A similar range of '“C ages has been obtained from Lucina shells taken from different stratigraphic intervals at the site (Widmer 2004). At the Miami Circle site no other types of volcanic material, such as obsidian, dense rhyolite, or basalt, have been discovered. Ground stone celts found at the Brickell Point excavations are composed of dark, aphanitic igneous rock that has a basaltic composition, however, the material most likely came from Mesozoic intrusive (diabase) dikes exposed in the Piedmont region of Georgia (Dixon et al. 2000). As a working hypothesis, it is assumed that the pumaceous material found at archeological sites in Florida is derived from oceanic drift material that washed ashore on beaches and may have been locally redistributed to inland communities. Inrecent times (1950s — present) a limited number of pumice clasts have washed ashore along the Atlantic coastline of Florida (Bryan 1972; Dennis 2000), however, the presence of such a large number of pieces of this exotic geologic material at the Miami Circle site may indicate that a relatively massive, short-term influx of pumice occurred along this portion of the shoreline of southeast Florida approximately 2000 years ago, or perhaps there was a long-term interest by native inhabitants in collecting sporadic occurrences of this material for use as tools or for ornamental purposes. The purpose of this study is to provide information on the physical and chemical characteristics of selected pumice samples for the Miami Circle site and other selected sites in Florida. Specific objectives of the study are to: (1) characterize the petrology (rock type) of the pumice artifacts; (2) use the mineralogy and chemistry of the samples to test for the homo- geneity of samples at one site and petrologic diversity between sites, and (3) test for the ultimate source of the pumice by comparing the observed petrologic and chemical characteristics of pumice artifacts with pumice samples collected from areas of recent volcanic activity in the circum-Atlantic, Caribbean and material from areas adjoining the western Gulf of Mexico. Sample Selection Twenty-two samples were selected for petrographic and geochemical studies. Five samples were selected from the Miami Circle site (8DA12). Pumice artifacts from sites in close proximity to the Miami Circle also were analyzed. These included two samples from the Brickell Point site (8DA98) and one from the Granada site (8DA11). An additional eleven pumice samples were analyzed for other sites in southern Florida and the Keys. Three pumice samples from the Wynnhaven Beach (80K2339) site, located on the Gulf Coast of northwestern Florida, also were analyzed. The locations of these sites, plus the locations of all other archeological sites known to contain pumice artifacts are shown in Figure 1. The specific site names and individual sample repository numbers are listed in Table 1. Sample Preparation Individual pumice samples were cut into slabs with a diamond saw to prepare the material for petrographic and geochemical analyses. The fresh surfaces of the pumice were observed using a low power, binocular microscope and physical characteristics (color, vesiculation and presence of pheoncrysts) were noted. Three samples were selected for scanning electron microscopy (SEM) studies. A small chip from each of these samples. was ultrasonically cleaned in acetone and then pro- cessed using standard SEM procedures. Petrographic thin sections for a selected subset of samples were prepared by vacuum impregnation of the porous rock with a blue dye epoxy, ere eeeneenr VOL, 59(3-4) THE FLORIDA ANTHROPOLOGIST SEPTEMBER- DECEMBER 2006