The influence of chemical composition of a soil upon the mass attenua- tion coefficient was also reported by Reginato and Van Bavel (72). They calculated theoretical values of g for 662 KeV photons for nine repre- sentative soils of the United States. Reginato (69), calculated mass at- tenuation coefficients of 60 KeV photons for the same soils. Coppola and Reiniger (10) extensively discussed the dependence of k upon chemical composition of soils and calculated attenuation coefficients for four soils over a range from 10 to 3000 KeV. B. Experimental Values Experimental determinations of mass attenuation coefficients for soil have provided values with magnitudes similar to theoretical values. Proper determination of mass attenuation coefficients requires a small standard deviation, good collimation of the radiation beam, a small dis- criminator window for the spectrometer, high intensity of the incident gamma beam, correction of counts for dead time, and use of optimum thickness of the soil sample. These factors have been discussed in other sections. In subsection B of section II the theoretical optimum thickness of the soil sample was discussed. However, if very great accuracy and pre- cision is needed in the measurement of mass attenuation coefficients, especially when the dual-energy gamma beam method is used, addi- tional considerations of the Compton effect is necessary. For example, if the sample thickness is large and the photon energy low, the Compton scattering influence increases and may become important to the ratio of radiation intensities (I/Io). Gopal and Sanjeevaiah (38) reported that an increase in the experi- mental value of g is due to the multiple scattering of gamma photons within the soil sample, which increases the counts. They studied the sample thickness influence upon f measurements and their investigations indicate that multiple scattering of photons could be minimized if the product of the mass attenuation coefficient times the sample thickness is less than one mean free path ([x